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The
gasification process includes four stages, each occurring in one of the four
separate zones within the gasifier: drying, pyrolysis, oxidation and reduction
zone.
Drying
In the
drying zone, moisture in the feedstock is evaporated by the heat from the lower
zones at a temperature of 150-200 degrees C. Vapours move down and mix with
vapours originating in the oxidation zone. A part of the vapours is converted
into oxygen under the following chemical reaction: С + H2 O
<=> CO +H2 with the remainder being retained in the producer
gas.
Pyrolysis
Located
below the Drying Zone, temperatures here reach 400 to 650 degrees C. Pyrolysis reactions occurt
temperatures above 250 degrees C. During pyrolysis,
large molecules such as cellulose, polycellulose and lignin, are broken down
into medium-chain hydrocarbons and carbon (charcoal). Pyrolysis products then
move down towards hotter areas within the gasifier, some of these burn while
the others break down further into smaller molecules and atoms such as
hydrogen, methane, carbon monoxide, ethane, ethylene, and others.
Oxidation
At this
level, air is injected into the gasifier, leading to the following chemical
reactions:
С + O2<=>
CO2
H + 1/2O2<=>
H2 O
These
reactions release large amounts of heat (401.9KJ/mol and 241.1 KJ/mol) that increase the temperature inside the gasifier to 900 – 1,200
degrees C. This assists with burning off a substantial part of tars that would
otherwise condense further downstream.
Reduction
In the
reduction zone, the thermal energy generated in the Oxidation zone is converted
into chemical energy in the following reactions:
C + CO2<=>
2CO
C + H2
O <=> CO + H2
CO + H2<=>
CO + H2 O
C + 2H2<=>
CH4
CO + 3H2<=>
CH4 + H2 O
These
reactions are endothermic and reduce the temperature of gas exiting the
Oxidation zone as it passes through the bed of charcoal at the bottom of the
gasifier. Producer gas in its final chemical composition is formed in this
zone. Upon leaving the gasifier this gas has temperatures of 250-500 degrees C
and can be fed to burners or, after additional cleaning and cooling, fired in internal combustion engines. |
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